among concentration, pH, and conductivity for sodium hydroxide levels typically found in caustic-only boilers. As was the case with ammonia, if the conductivity is known, the pH and sodium hydrox-ide concentration are automatically known. However, if electrolytes other than sodium hydroxide are present, the pH inferred from Figure 3 will be in
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alkalinity is achieved by dosing tri-sodium phosphate to the boiler water such as sodium phosphate or sodium hydroxide, reduces the effects of corrosive impurities and flow-accelerated corrosion, the use of phosphate (PT) and NaOH treatments in the boiler/HRSG evaporator can lead to a pH. 11, ..,,
Download scientific diagram | Conductivity and pH of boiler water when using tri-sodium phosphate. from publication: Using of congruent phosphate as equilibrium phosphate boilers water treatment
2. Phosphate Treatment (PT) –Various regimes based on use of several sodium phosphate salts; only the use of Tri-Sodium Phosphate is recommended. 3. Caustic Treatment (CT) –Sodium Hydroxide Where boiler pressure (and discharges to water) allow, the use of Tri-Sodium Phosphate is preferred instead of Caustic as the corrosion risks are usually
Jun 26, 2017 · B. Sodium sulfite dosage. Once the oxygen content of the feedwater has been estimated, the sulfite dosages can be calculated. The sulfite dosage is the sum of the ppm needed to neutralize the dissolved oxygen, plus additional amounts needed to produce an acceptable boiler water residual.
Nov 01, 2007 · Common boiler water treatment chemicals are sodium hydroxide and sodium phosphate salts. Except for trace amounts carried over with the steam, solid treatment chemicals remain in the boiler.
Jan 27, 2013 · Pressure of HP drum is 120. We have facing problem of low pH (5-8) and Low PO4 in HP drum in spite of continuous dosing of Tri Sodium Phosphate. Conductivity of boiler water is also high, i.e., about 200 µs/cm. While Feed, Hot well condensate pH and steam pH is ok. We're dosing Ammonia and Hydrazine in feed water system.
Sulfite is commonly supplied as sodium sulfite, Na 2SO 3; sodium bisulfite, NaHSO 3; ammonium sulfite, (NH 4) 2SO 3; or sodium metabisulfite, Na 2S 2O 5. Sodium sulfite can decompose to sulfur dioxide (SO 2)and hydrogen sulfide (H 2S) in the boiler. For this reason, the use of sulfites is limited to boilers …
A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the phosphate, determining the concentration of the phosphate-feed tracer in the phosphate-feed stream and correlating the phosphate-feed
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Caustic attack on boilers is a localized attack due to extremely high pH (12.9 +). It can take two forms: caustic gouging or caustic cracking, also called caustic embrittlement. Caustic attack or caustic corrosion, is often encountered in phosphate treated boilers in which deposits of phosphates or other 'scale' occur in high heat transfer
Why is phosphate dosing done in a boiler? - Quora
Phosphate Hideout. When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere. This phenomenon is called phosphate hideout and it can result in changes of pH, as well as the
Apr 27, 2015 · These include sodium phosphate, chelating agents like EDTA, and synthetic polymers. Two forms of sodium phosphate find application in low and medium pressure boilers; disodium phosphate (NaHPO4 having a 49% P2O5 content) and sodium metaphosphate (NaPO3 having a 69% P2O5 content). Both react under boiler conditions to produce orthophosphate (o-PO4).
boiler. Generally these products should be dosed into the boiler feed tank, especially if sodium bisulphite is used, as this is acidic. Generally it is desirable to have a slightly high pH for boiler feed water. Ideally the feed water should be in the range of pH 8.5 – 9.5. This ensures that free carbon dioxide within the system becomes
The original solution will be buffered at a pH of around 12, whereas the new mixture will naturally form a buffer with water as N a H 2 P O 4 / N a 2 H P O 4 at a pH around but just above 7. [ 1] Given this is being used in a boiler, the lower pH will increase the risk of acid attack corrosion. The higher pH with the N a 2 H P O 4 / N a 3 P O 4 would possibly have a slight increase risk of scale, but shouldn't be sufficient to …
Feb 07, 2016 · To eliminate the problem of caustic embrittlement use sodium phosphate instead of sodium carbonate as softening reagents. Adding tannin or lignin to boiler …
Jul 21, 2020 · Phosphate reacts with calcium and magnesium forms less sticky, loose and non-adherent sludge instead of hard scale. This sludge remains in the boiler water in suspended condition and then, removed from the boiler through blow down Other than TSP, disodium phosphate (Na2HPO4) and monosodium phosphate (NaH2PO4) are used in boiler for dosing.